PREPARATION OF COLLOIDAL SILVER USING VARIOUS REDUCTANTS IN THE PRESENCE OF COPOLYMERS OF VINYL ALCOHOL-N-VINYL PYRROLIDONE

被引：9

作者：

ESUMI, K

ISHIZUKI, N

TORIGOE, K

NAKAMURA, H

MEGURO, K

机构：

[1] Department of Applied Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo, Tokyo, 162, Kagurazaka, Shinjuku‐ku

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1992年 / 44卷 / 06期

关键词：

D O I：

10.1002/app.1992.070440609

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Colloidal silver was prepared using various reductants such as hydrazine, ascorbic acid, ribose, and hydrogen in aqueous solution in the presence of copolymers of vinyl alcohol-N-vinyl pyrrolidone. The average particle size of colloidal silver decreased with increasing amount of copolymers added. The reduction by hydrogen provided smaller silver particles compared with the other reductants. The stability of colloidal silver against AlCl3 increased with increasing amount of copolymers added.

引用

页码：1003 / 1007

页数：5

共 19 条

[11] THE PREPARATION OF COLLOIDAL PRECIOUS METAL PARTICLES USING COPOLYMERS OF VINYL ALCOHOL-N-VINYLPYRROLIDONE [J].

MEGURO, K ;

NAKAMURA, Y ;

HAYASHI, Y ;

TORIZUKA, M ;

ESUMI, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (02) :347-350

[12]

Napper D H., 1983, POLYM STABILIZATION, Vvol. 3

[13]

SINGER LA, 1982, SOLUTION BEHAVIOR SU, V1, P73

[14] FORMATION AND AGING OF PRECIPITATES .8. FORMATION OF MONODISPERSE PARTICLES (1) GOLD SOL PARTICLES BY SODIUM CITRATE METHOD [J].

TAKIYAMA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1958, 31 (08) :944-+

[15]

TANAKA T, 1982, SHOKUBAI, V24, P373

[16]

TATSUYA S, 1977, KOTAI BUTSURI, V12, P231

[17] A STUDY OF THE NUCLEATION AND GROWTH PROCESSES IN THE SYNTHESIS OF COLLOIDAL GOLD [J].

TURKEVICH, J ;

STEVENSON, PC ;

HILLIER, J .

DISCUSSIONS OF THE FARADAY SOCIETY, 1951, (11) :55-&

[18]

UDA M, 1983, KAGAKU KOGYO, V36, P518

[19]

WESTERHAUSEN J, 1981, BER BUNSEN PHYS CHEM, V85, P181

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