ACID-BASE BEHAVIOR OF SOME SUBSTITUTED AZO DYES IN AQUEOUS N, N-DIMETHYLFORMAMIDE MIXTURES

被引:17
|
作者
GONZALEZ, AG
HERRADOR, MA
ASUERO, AG
机构
[1] Department of Analytical Chemistry, University of Seville
关键词
SPECTROPHOTOMETRY; ACID-BASE EQUILIBRIA; AZO DYES; DISSOCIATION CONSTANTS;
D O I
10.1016/S0003-2670(00)80982-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The dissociation constants of six azo dye indicators were evaluated spectrophotometrically in 10-80% (v/v) N,N-dimethylformamide-water mixtures at 25 +/- 0.1-degrees-C, by applying an empirical pH correction. The acid-base behaviour of these indicators in the media studied is explained on the basis of electrostatic and hydrophobic interactions between the indicators and the solvent.
引用
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页码:429 / 434
页数:6
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