SURFACE-MEDIATED REACTIONS .5. OXIDATION OF SULFIDES, SULFOXIDES, AND ALKENES WITH TERT-BUTYL HYDROPEROXIDE

被引：53

作者：

BRETON, GW ^{[1
]}

FIELDS, JD ^{[1
]}

KROPP, PJ ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 22期

关键词：

D O I：

10.1016/0040-4039(95)00688-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silica gel mediates the reactivity of (CH3)(3)COOH, affording a convenient, environmentally benign method for oxidizing sulfides, sulfoxides, and alkenes. Electrophilic oxidation of sulfides and alkenes (Scheme 1A) and nucleophilic oxidation of sulfoxides (Scheme 1B) are apparently involved. Basic alumina mediates the oxidation of sulfoxides.

引用

页码：3825 / 3828

页数：4

共 15 条

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