ENANTIOSELECTIVE EPOXIDATION OF UNFUNCTIONALIZED ALKENES USING DIOXIRANES GENERATED IN-SITU

被引：99

作者：

CURCI, R

D'ACCOLTI, L

FIORENTINO, M

ROSA, A

机构：

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 32期

关键词：

D O I：

10.1016/0040-4039(95)01108-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using (+)-3-(trifluoroacetyl)camphor, or R(+)- and S(-)-3-methoxy-3-phenyl-4,4,4-trifluoro-butan-2-one as precursors for chiral dioxiranes generated in situ, the asymmetric epoxidation of prochiral alkenes trans-beta-methylstyrene, trans-2-octene, and cis-2-methyl-7-octadecene has been achieved in 12-20% ee.

引用

页码：5831 / 5834

页数：4

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