ENANTIOSELECTIVE EPOXIDATION OF UNFUNCTIONALIZED ALKENES USING DIOXIRANES GENERATED IN-SITU

被引：99
|
作者：
CURCI, R
D'ACCOLTI, L
FIORENTINO, M
ROSA, A
机构：
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 32期
关键词：
D O I：
10.1016/0040-4039(95)01108-T
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Using (+)-3-(trifluoroacetyl)camphor, or R(+)- and S(-)-3-methoxy-3-phenyl-4,4,4-trifluoro-butan-2-one as precursors for chiral dioxiranes generated in situ, the asymmetric epoxidation of prochiral alkenes trans-beta-methylstyrene, trans-2-octene, and cis-2-methyl-7-octadecene has been achieved in 12-20% ee.
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页码：5831 / 5834
页数：4
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