ACTIVITY OF GAMMA-AL2O3 MODIFIED BY NAOH IN DISPROPORTIONATION OF METHANETHIOL

被引：7
作者：
MASHKINA, AV
GRUNVALD, VR
BORODIN, BP
NASTEKA, VI
YAKOVLEVA, VN
KHAIRULINA, LN
机构：
[1] VOLGOURAL NIPI GAZ,ORENBURG,USSR
[2] NOVOSIBIRSK CATALYSIS INST,NOVOSIBIRSK 630090,USSR
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 43卷 / 02期
关键词：
D O I：
10.1007/BF02064698
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Na+/Al2O3 catalysts in disproportionation of methanethiol are highly selective towards dimethyl sulfide but less active compared to gamma-Al2O3. Their activity falls with increasing Na+ in the sample. This decrease is due to the neutralization of Bronsted acid centers on the catalyst.
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页码：361 / 365
页数：5
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