A METHYL FREE-RADICAL SOURCE FOR USE IN SURFACE STUDIES

被引:75
作者
PENG, XD
VISWANATHAN, R
SMUDDE, GH
STAIR, PC
机构
关键词
D O I
10.1063/1.1143240
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A methyl radical source has been developed for use in high vacuum. Methyl radicals are produced through azomethane pyrolysis in a tubular reactor located inside an ultrahigh vacuum chamber. Other gas products include nitrogen from azomethane pyrolysis, and methane, ethane plus hydrogen from the reactions of methyl radicals on the walls of the walls of the reactor. Methyl yields as high as 42% have been observed.
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页码:3930 / 3935
页数:6
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