NONEQUILIBRIUM GLOW-DISCHARGE FLUORINATION OF POLYMER SURFACES

被引:65
作者
HOPKINS, J [1 ]
BADYAL, JPS [1 ]
机构
[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND
关键词
D O I
10.1021/j100012a056
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CF4 plasma treatment of a range of polymers (polyethylene, polypropylene, polyisoprene, polystyrene, polyether ether ketone, polyethylene terephthalate, polycarbonate, polysulfone, and polyether sulfone) has been investigated by X-ray photoelectron spectroscopy (XPS). A correlation is found to exist between the level of fluorine incorporation into the surface and the chemical structure of the parent polymer. This experimental observation can be rationalized on a theoretical basis in terms of results obtained from extended Huckel molecular orbital calculations.
引用
收藏
页码:4261 / 4264
页数:4
相关论文
共 32 条
[11]  
EGITTO DF, 1990, PLASMA DEPOSITION TR, pCH5
[12]   PLASMA-ETCHING AND MODIFICATION OF ORGANIC POLYMERS [J].
EGITTO, FD .
PURE AND APPLIED CHEMISTRY, 1990, 62 (09) :1699-1708
[13]   REACTIVE ION ETCHING OF POLY(TETRAFLUOROETHYLENE) IN O2-CF4 PLASMAS [J].
EGITTO, FD ;
MATIENZO, LJ ;
SCHREYER, HB .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1992, 10 (05) :3060-3064
[14]  
EHRLICH CD, 1992, J VAC SCI TECHNOL A, V10, P1, DOI 10.1116/1.578137
[15]   ANGLE RESOLVED ESCA ANALYSIS OF PLASMA MODIFIED POLYSTERENE [J].
EVANS, JF ;
GIBSON, JH ;
MOULDER, JF ;
HAMMOND, JS ;
GORETZKI, H .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1984, 319 (6-7) :841-844
[16]   VACUUM-ULTRAVIOLET-INDUCED OXIDATION OF POLYETHYLENE [J].
HOLLANDER, A ;
KLEMBERGSAPIEHA, JE ;
WERTHEIMER, MR .
MACROMOLECULES, 1994, 27 (10) :2893-2895
[17]   HYDROPHOBIC POLYMER-FILMS PLASMA-POLYMERIZED FROM CF4 HYDROCARBON AND HEXAFLUROACETONE HYDROCARBON MIXTURES [J].
INAGAKI, N ;
TASAKA, S ;
MORI, K .
JOURNAL OF APPLIED POLYMER SCIENCE, 1991, 43 (03) :581-588
[18]   FUNDAMENTAL ASPECT AND BEHAVIOR OF SATURATED FLUOROCARBONS IN GLOW-DISCHARGE IN ABSENCE OF POTENTIAL SOURCE OF HYDROGEN [J].
IRIYAMA, Y ;
YASUDA, H .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (08) :1731-1739
[19]  
Kay E., 1983, Proceedings of the International Ion Engineering Congress. The 7th Symposium (1983 International) on Ion Sources and Ion Assisted Technology (ISIAT '83) and the 4th International Conference on Ion and Plasma Assisted Techniques (IPAT '83), P1657
[20]  
KLAUSNER M, 1987, POLYM MATER SCI ENG, V56, P227