NONEQUILIBRIUM GLOW-DISCHARGE FLUORINATION OF POLYMER SURFACES

被引：65

作者：

HOPKINS, J ^{[1
]}

BADYAL, JPS ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 12期

关键词：

D O I：

10.1021/j100012a056

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CF4 plasma treatment of a range of polymers (polyethylene, polypropylene, polyisoprene, polystyrene, polyether ether ketone, polyethylene terephthalate, polycarbonate, polysulfone, and polyether sulfone) has been investigated by X-ray photoelectron spectroscopy (XPS). A correlation is found to exist between the level of fluorine incorporation into the surface and the chemical structure of the parent polymer. This experimental observation can be rationalized on a theoretical basis in terms of results obtained from extended Huckel molecular orbital calculations.

引用

页码：4261 / 4264

页数：4

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