TRANSITION METAL-CATALYZED N-ALKYLATION OF NH GROUPS OF AZOLES WITH ALCOHOLS

被引：38

作者：

TANAKA, N ^{[1
]}

HATANAKA, M ^{[1
]}

WATANABE, Y ^{[1
]}

机构：

[1] KYOTO UNIV, DEPT HYDROCARBON CHEM, SAKYO KU, KYOTO 606, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 04期

关键词：

D O I：

10.1246/cl.1992.575

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Azoles containing acidic NH-group react with various alcohols in the presence of catalytic amount of ruthenium-, rhodium-, and iridium-trialkylphosphite complexes to give the corresponding N-alkylated azoles in good to excellent yields.

引用

页码：575 / 578

页数：4

共 16 条

[1]

AATALAN J, 1987, ADV HETEROCYCLIC CHE, V41, P187

[2] SELECTIVE CONVERSION OF PRIMARY AMINES INTO N,N-DIMETHYLALKYL-AMINE OR N,N-DIALKYLMETHYL-AMINE WITH METHANOL AND RUCL2(PH3P)3 [J].

ARCELLI, A ;

BUITHEKHAI ;

PORZI, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 235 (01) :93-96

[3] HOMOGENEOUS OLEFIN HYDROGENATION CATALYZED BY DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) [J].

FAHEY, DR .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (19) :3343-3348

[4]

GIBSON MS, 1968, CHEM AMINO GROUP, P45

[5] TRANSITION METAL-CATALYZED N-ALKYLATION OF AMINES BY ALCOHOLS [J].

GRIGG, R ;

MITCHELL, TRB ;

SUTTHIVAIYAKIT, S ;

TONGPENYAI, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (12) :611-612

[6] PREPARATION AND REACTIONS OF HYDRIDOCHLOROTRIS(TRIPHENYLPHOSPHINE)-RUTHENIUM(2) INCLUDING HOMOGENEOUS CATALYTIC HYDROGENATION OF ALK-1-ENES [J].

HALLMAN, PS ;

MCGARVEY, BR ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (12) :3143-+

[7] HOMOGENEOUS CATALYTIC HYDROGENATION OF OLEFINIC COMPOUNDS [J].

HALPERN, J ;

HARROD, JF ;

JAMES, BR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (03) :753-&

[8]

HIRINO H, 1978, CHEM LETT, P17

[9] TRANSFER HYDROGENATION AND TRANSFER HYDROGENOLYSIS .9. HYDROGEN TRANSFER FROM ORGANIC COMPOUNDS TO ALDEHYDES AND KETONES CATALYZED BY DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) [J].

IMAI, H ;

NISHIGUCHI, T ;

FUKUZUMI, K .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (04) :665-671

[10]

Malpase J. R, 1979, COMPREHENSIVE ORGA 6, V2, P4

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