NEOCLERODANE DITERPENOIDS FROM SCUTELLARIA-DRUMMONDII

被引：19
作者：
ESQUIVEL, B
FLORES, E
HERNANDEZORTEGA, S
TOSCANO, RA
机构：
[1] Instituto de Química de la Universidad Nacional Autónoma de México, Circuito Exterior de Cd. Universitaria
来源：
PHYTOCHEMISTRY | 1995年 / 38卷 / 01期
关键词：
SCUTELLARIA DRUMMONDII; LABIATAE; NEOCLERODANE DITERPENES; 2-ALPHA-HYDROXYAJUGARIN V; 2-ALPHA-HYDROXY-DEACETYLAJUGARIN V; SCUTEDRUMMONIN;
D O I：
10.1016/0031-9422(94)00531-W
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Three new neo-clerodane diterpenoids, 6 alpha-acetoxy-4 alpha,18-epoxy-2 alpha-hydroxy-13-neocleroden-15,16-olide (2 alpha-hydroxyajugarin V), 4 alpha,18-epoxy-2 alpha,6 alpha-dihydroxy-13-neocleroden-15,16-olide (2 alpha-hydroxy-deacetylajugarin V) and 2 alpha,6 alpha-dihydroxy-4(18), 13-neoclerodadien-15,16-olide (scutedrummonin), have been isolated from the aerial parts of Scutellaria drummondii, in addition to the known flavone xanthomicrol. The structures of the new diterpenoids were established by chemical and spectroscopic means, including X-ray diffraction analysis for 2 alpha-hydroxyajugarin V.
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页码：175 / 179
页数：5
相关论文
共 25 条
[1]  
ALTOMARE A, 1993, IN PRESS J APPL CRYS, V26
[2]   THE STRUCTURE OF 2 NEW CLERODANE DITERPENOID POTENT INSECT ANTIFEEDANTS FROM SCUTELLARIA-WORONOWII (JUZ) - JODRELLIN-A AND JODRELLIN-B [J].
ANDERSON, JC ;
BLANEY, WM ;
COLE, MD ;
FELLOWS, LL ;
LEY, SV ;
SHEPPARD, RN ;
SIMMONDS, MSJ .
TETRAHEDRON LETTERS, 1989, 30 (35) :4737-4740
[3]  
[Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[4]   A CLERODANE DITERPENE FROM AJUGA-SALICIFOLIA [J].
BOZOV, PI ;
PAPANOV, GY ;
MALAKOV, PY ;
DELATORRE, MC ;
RODRIGUEZ, B .
PHYTOCHEMISTRY, 1993, 34 (04) :1173-1175
[5]   SCUTALPIN-A, A NEOCLERODANE DITERPENE FROM SCUTELLARIA-ALPINA [J].
BOZOV, PI ;
MALAKOV, PY ;
PAPANOV, GY ;
DELATORRE, M ;
RODRIGUEZ, B ;
PERALES, A .
PHYTOCHEMISTRY, 1993, 34 (02) :453-456
[6]   A NEOCLERODANE DITERPENOID FROM SCUTELLARIA-CYPRIA VAR ELATIOR [J].
BRUNO, M ;
DELATORRE, MC ;
PIOZZI, F ;
RODRIGUEZ, B ;
SAVONA, G ;
ARNOLD, NA .
PHYTOCHEMISTRY, 1993, 33 (04) :931-932
[7]   ANTIFUNGAL ACTIVITY OF NEOCLERODANE DITERPENOIDS FROM SCUTELLARIA [J].
COLE, MD ;
BRIDGE, PD ;
DELLAR, JE ;
FELLOWS, LE ;
CORNISH, MC ;
ANDERSON, JC .
PHYTOCHEMISTRY, 1991, 30 (04) :1125-1127
[8]   NEOCLERODANE INSECT ANTIFEEDANTS FROM SCUTELLARIA-GALERICULATA [J].
COLE, MD ;
ANDERSON, JC ;
BLANEY, WM ;
FELLOWS, LE ;
LEY, SV ;
SHEPPARD, RN ;
SIMMONDS, MSJ .
PHYTOCHEMISTRY, 1990, 29 (06) :1793-1796
[9]   GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].
CREMER, D ;
POPLE, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358
[10]   NEOCLERODANE DITERPENOIDS FROM SCUTELLARIA-COLUMNAE [J].
DELATORRE, MC ;
BRUNO, M ;
PIOZZI, F ;
RODRIGUEZ, B ;
SAVONA, G ;
SERVETTAZ, O .
PHYTOCHEMISTRY, 1992, 31 (10) :3639-3641
123