THEORY OF SOLVATED ELECTRON IN POLAR LIQUIDS .I. ORIENTED DIPOLE MODEL

被引：42

作者：

IGUCHI, K

机构：

[1] Department of Fundamental Chemistry, School of Science and Engineering, Waseda University, Nishi-Okubo, Shinjuku-ku

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 04期

关键词：

D O I：

10.1063/1.1668902

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A model is proposed for the solvated electron in polar liquids, in which molecular dipoles are assumed to orient spherically around the electron. The potential field due to this orientation, the energy levels, the absorption peak and its temperature dependence, and the heat of solvation are calculated at various temperatures. Calculated absorption peak E = 1.69 eV (300°K), 1.89 eV (180°K), and ∂ΔE/∂T = 0.16 eV deg-1 are compared with experimental data, and they show a fairly good agreement.

引用

页码：1735 / &