REACTION OF CH3O2+HO2 IN AIR AT 295-K - A PRODUCT STUDY

被引：56

作者：

WALLINGTON, TJ

JAPAR, SM

机构：

[1] Ford Motor Company, Dearborn, MI 48121

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 167卷 / 06期

关键词：

D O I：

10.1016/0009-2614(90)85461-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fourier transform infrared spectroscopy was used to identify and quantify methylhydroperoxide as the dominant product of the gas phase reaction of methylperoxy radicals with hydroperoxy radicals. At 295 K, and 700 Torr total pressure of air, 92±8% of the reaction of CH3O2 with HO2 proceeds via CH3O2+HO2→CH3OOH+O2. Results are discussed with respect to the previous kinetic and mechanistic studies of peroxy radicals and computer models of atmospheric chemistry. © 1990.

引用

页码：513 / 518

页数：6

共 17 条

[1] EVALUATED KINETIC AND PHOTOCHEMICAL DATA FOR ATMOSPHERIC CHEMISTRY .3. IUPAC SUBCOMMITTEE ON GAS KINETIC DATA EVALUATION FOR ATMOSPHERIC CHEMISTRY [J].