INELASTIC PROCESSES AND INTERACTION ANISOTROPY FOR H- COLLISIONS WITH H-2

被引：14
|
作者：
GIANTURCO, FA
KUMAR, S
机构：
[1] Department of Chemistry, University of Rome, Città Universitaria
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 42期
关键词：
D O I：
10.1021/j100042a004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vibrationally inelastic processes which can occur in collisions of low-energy simple negative ions with diatomic molecules are studied by using the H--H-2 system and by applying to it the quantum treatment of the relevant multichannel scattering theory. The unusual behavior of the vibrationally inelastic cross sections, integral and differential, is linked to specific features of the lowest-lying potential-energy surface, and microscopic effects of such features on the dynamics are discussed in relation to what was found earlier for the H+-H-2 system.
引用
收藏
页码：15342 / 15347
页数：6
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