PHOTOCHEMICAL-REACTION OF 2-AZABICYCLO[3.1.0]HEX-3-ENE - THE FORMATION OF 1-AZAHEXATRIENES AND THE CYCLIZATION TO 1,2-DIHYDROPYRIDINE

被引：13

作者：

KUMAGAI, T

SAITO, S

EHARA, T

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University Sendai

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 47期

关键词：

PHOTOLYSIS; HOMOPYRROLE; DIHYDROPYRIDINE; AZAHEXATRIENE; ELECTROCYCLIZATION;

D O I：

10.1016/0040-4039(91)80437-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The irradiation of homopyrrole gives rise to 1-azahexatrienes which are thermally cyclized to 1,2-dihydropyridine and provide the methanol-adducts in the presence of methanol. The photolysis of dihydropyridine at low temperature affords a mixture of the same azatrienes.

引用

页码：6895 / 6898

页数：4