TRIS(2,6-DIMETHOXYPHENYL)BORANE AND ITS ADDUCTS

被引：7

作者：

WADA, M

KANZAKI, M

OGURA, H

HAYASE, S

ERABI, T

机构：

[1] Department of Materials Science, Faculty of Engineering, Tottori University, Tottori, 680, Koyama

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 485卷 / 1-2期

关键词：

BORON; 2,6-DIMETHOXYPHENYL; BORATE; AMINE; PHOSPHONIUM; SOLUBILITY;

D O I：

10.1016/0022-328X(94)24763-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(2,6-dimethoxyphenyl)borane, Phi(3)B (Phi = 2,6-(MeO)(2)C6H3), an air-stable crystalline compound, formed isolable 1:1 adducts with ammonia and some primary amines but not with tertiary amines, secondary amines, or sec-alkylamines. Some tetraalkylammonium tris(2,6-dimethoxyphenyl)cyanoborates [R,N][Phi(3)B-CN] are soluble both in water and in benzene, and the stearyltrimethylammonium salt is soluble even in n-hexane. The freezing point depression measurements for some tetraalkylammonium salts suggested that they are associated in benzene by several molecules.

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页码：127 / 133

页数：7

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