CATALYTIC TRANSFORMATIONS OF 3-CARENE OXIDE OVER ALUMINA-RARE EARTH OXIDE CATALYSTS

被引：0

作者：

JAYASREE, J

NARAYANAN, CS

机构：

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1995年 / 34卷 / 07期

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中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isomerization of 3-carene oxide over binary oxide catalysts like Al2O3-Y2O3, Al2O3-Sm2O3, Al2O3-Eu2O3, Al2O3-Pr6O11 and Al2O3-Nd2O3 at 80 degrees C and 110 degrees C has been studied. 3,6,6-Trimethyl-bicyclo[3.1.0]hexane-3-carboxaldehyde and caranone are the major products formed at 80 degrees C. Rise in reaction temperature results in an increase in epoxide transformation and an irregular variation in the yield of products.

引用

页码：577 / 580

页数：4

共 20 条

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