FORMATION OF A TRINUCLEAR MU(3)-METHYLIDYNE COMPLEX, (MU(3)-CH)[MOCP(CO)(2)](3), THROUGH REDUCTION OF A CO-LIGAND IN CP(2)MO(2)(CO)(4) BY A HYDROSILANE

被引：20

作者：

AKITA, M

NODA, K

MOROOKA, Y

机构：

[1] Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Yokohama 227, 4259 Nagatsuta, Midori-ku

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1021/om00023a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of a benzene solution of Cp(2)Mo(2)(CO)(4) (1) and HSiMe(2)Ph results in reduction of CO to give art isomeric mixture of the trimolybdenum mu(3)-methylidyne complex (mu(3)-CH)[MoCp(CO)(2)](3) (2) with semibridging CO ligands. Crystallographic and spectroscopic analyses of 2 reveal complicated dynamic behavior by way of gearlike rotation and local rotation of the CpMo(CO)(2) unit(s) accompanying switching of the semibridging CO ligands.

引用

页码：4145 / 4147

页数：3

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