3'-(2,6-DICHLOROPHENYL)BICYCLO[2.2.1]-HEPTANE-2-SPIRO-5'(4'H)-ISOXAZOLE-3-ONE

被引：4
|
作者：
MACKAY, MF [1 ]
SAVAGE, GP [1 ]
SIMPSON, GW [1 ]
机构：
[1] CSIRO,DIV CHEM & POLYMERS,CLAYTON,VIC 3168,AUSTRALIA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S0108270194004622
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, C15H13Cl2NO2, resulted from a 1,3-dipolar cycloaddition (a class of reactions of significant importance in heterocyclic chemistry). The isoxazole ring atoms are coplanar to within 0.05 (1) Angstrom and the cyclohexanone ring of the norbornanone moiety adopts the expected boat form with the two five-membered rings in envelope conformations. The orientation of the isoxaxole ring to the cyclohexanone ring is given by the torsion angles O1'-C2-C3-O3 71.7 (4) and C4'-C2-C1-C6 -64.0 (4)degrees. The dihedral angle between the isoxazole and 2,6-dichlorophenyl rings is 73.3 (3)degrees.
引用
收藏
页码：1772 / 1774
页数：3
相关论文
共 50 条
  • [1] 3-benzylidene-1-(2,6-dichlorophenyl)indolin-2-one
    Thamotharan, S
    Parthasarathi, V
    Vijayalakshmi, L
    Anuradha, B
    Desai, B
    Shah, A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : o885 - o886
  • [2] 3′′′-(2,6-dichlorophenyl)-1′-methyl-4′,4′′′-diphenyl-4′′′,5′′′-dihydro-indole-3-spiro-2′-pyrrolidine-3′-spiro-1"-cydopentane-3"-spiro-5′′′-[1,2]oxazole-2(3H),2"-dione
    Li, XF
    Feng, YQ
    Gao, B
    Li, N
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1659 - O1660
  • [3] 1′-benzyl-3-(2,6-dichlorophenyl)-1"-methyl-4,4"-diphenyloxazole-5(4H)-spiro-3′-piperidine-5′-spiro-3"-pyrrolidine-2"-spiro-3"′-1H-indole-2"′(3"′H),4′-dione benzene hemisolvate
    Li, XF
    Feng, YQ
    Hu, XF
    Xu, M
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1280 - O1282
  • [4] 2-(2,6-Dichlorophenyl)-3-(quinolin-2-yl)thiazolidin-4-one
    Raghunandan, Resmi
    Rawal, Ravindra K.
    Katti, S. B.
    Maulik, Prakas R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5349 - O5351
  • [5] N-(2,6-Dichlorophenyl)-3-methylbenzamide
    Gowda, B. Thimme
    Tokarcik, Miroslav
    Kozisek, Jozef
    Rodrigues, Vinola Zeena
    Fuess, Hartmut
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2713 - U437
  • [6] 3-(2,6-Dichlorophenyl)-3-hydroxy-1-phenyl-propan-1-one
    Luo, XX
    Shan, ZX
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1197 - O1198
  • [7] 1-Benzoyl-3-(2,6-dichlorophenyl)thiourea
    Rauf, MK
    Badshah, A
    Flörke, U
    Saeed, A
    Saeed, MA
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1264 - O1265
  • [8] 3-Acetyl-1-(2,6-dichlorophenyl)thiourea
    Kumar, Sharatha
    Foro, Sabine
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02307 - +
  • [9] 4-(2,6-Dichlorophenyl)-1,4-dihydroxybutan-2-one
    He, Long
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O38 - O39
  • [10] 2,3,5,6-TETRAMETHYLIDENE-BICYCLO[2.2.1]HEPTANE - PRELIMINARY COMMUNICATION
    FLOREY, A
    VOGEL, P
    HELVETICA CHIMICA ACTA, 1975, 58 (05) : 1488 - 1492
12345