ELECTROCHEMISTRY OF ORGANOSILICON COMPOUNDS .1. SYNTHESIS OF DISILANES AND TRISILANES WITH USE OF MERCURY AND SILVER ELECTRODE SYSTEMS

被引：40

作者：

KUNAI, A

KAWAKAMI, T

TOYODA, E

ISHIKAWA, M

机构：

[1] Department of Applied Chemistry, Hiroshima University

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 04期

关键词：

D O I：

10.1021/om00050a018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical formation of an Si-Si bond has been examined. Electrolysis of monochlorosilanes in 1,2-dimethoxyethane using a platinum cathode and a mercury anode gave disilanes in high yield, while the electrolysis of a mixture of two different monochlorosilanes produced unsymmetrical disilanes as main products. Similar treatment of a mixture of monochlorosilanes and dichlorosilanes gave trisilanes. The use of silver as the anode also gave the di- and trisilanes in high yields.

引用

页码：893 / 895

页数：3

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[1] A SURVEY OF CATALYTIC ACTIVITY OF ETA-5-CYCLOPENTADIENYL COMPLEXES OF GROUPS 4-6 AND URANIUM AND THORIUM FOR THE DEHYDROCOUPLING OF PHENYLSILANE [J].