COORDINATION OF DIOXYGEN IN 3 REPRESENTATIVE TRANSITION-METAL CATIONS - FEO2+ CRO2+ AND [CH3RE(O-2)(2)O](+)

被引：30
|
作者：
SCHRODER, D
FIEDLER, A
HERRMANN, WA
SCHWARZ, H
机构：
[1] TECH UNIV BERLIN,INST ORGAN CHEM,D-10623 BERLIN,GERMANY
[2] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8000 MUNICH,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期
关键词：
AB INITIO CALCULATIONS; OXYGEN ACTIVATION; MASS SPECTROMETRY; TRANSITION METAL OXIDES;
D O I：
10.1002/anie.199525171
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
How is dioxygen activated by “naked” or ligated metals? Details of the potential energy surfaces of the three representative cations [Fe,O2]+, [Cr,O2]+, and [CH3Re(O2)2O]+ were correlated with mass spectrometric data. The results may lead to a better understanding of O2 activation in synthetic, industrial, and biological processes. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码：2517 / 2520
页数：4
相关论文
共 50 条
12345