GRAIN-SIZE EFFECTS ON DIFFUSE PHASE-TRANSITIONS OF SOL-GEL PREPARED BARIUM-TITANATE CERAMICS

被引：57

作者：

LOBO, RPSM ^{[1
]}

MOHALLEM, NDS ^{[1
]}

MOREIRA, RL ^{[1
]}

机构：

[1] UNIV FED MINAS GERAIS,ICEX,DEPT QUIM,BR-30161 BELO HORIZONT,MG,BRAZIL

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1995年 / 78卷 / 05期

关键词：

D O I：

10.1111/j.1151-2916.1995.tb08492.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Barium titanate ceramic samples, obtained by sol-gel methods, having different grain sizes have been analyzed by diffuse phase transition techniques. We performed a study of the influence of each method on the phase transition interval and on the Landau parameters of the ferroelectric phase transition of these materials. The results show the existence of a relationship between the diffuse character of the transition and the grain size of the sample. The method of fitting dielectric data presented here allows us to compare ceramics with single crystals and then analyze the sol-gel process used to obtain them.

引用

页码：1343 / 1346

页数：4

共 25 条

[1]

Kinoshita K., Yamaji A., Grain‐Size Effects on Dielectric Properties in Barium Titanate Ceramics, J. Appl. Phys., 47, 1, pp. 371-373, (1976)

[2]

Yamaji A., Enomoto Y., Kinoshita K., Murakami T., Preparation, Char‐acterization, and Properties of Dy‐Doped Small‐Grained BaTiO3 Ceramics, J. Am. Ceram. Soc., 60, 3-4, pp. 97-101, (1977)

[3]

Bell A.J., Moulson A.J, Cross L.E., The Effect of Grain Size on the Permittivity of BaTiO3, Ferroelectrics., 54, pp. 147-150, (1984)

[4]

Arlt G., Hennings D., de With G., Dielectric Properties of Fine‐Grained Barium Titanate Ceramics, J. Appl. Phys., 58, 4, pp. 1619-1625, (1985)

[5]

Kanata T., Yoshikawa T., Kubota K., Grain‐Size Effects on the Dielectric Phase Transition of BaTiO3 Ceramics, Solid State Commun., 62, 11, pp. 765-767, (1987)

[6]

Arlt G., The Influence of Microstructure on the Properties of Ferroelectric Ceramics, Ferroelectrics, 104, pp. 217-227, (1990)

[7]

Mohallem N.D.S., (1990)

[8]

Zhixiong C., Fangqiao Z., Meidong L., Guoan W., Xiangsheng P., Sol—Gel Derived BaTiO3 Ceramics, Ferroelectrics, 123, pp. 61-67, (1991)

[9]

Smolensky G.A., Isupov V.A., Ferroelectric Properties of Solid Solutions of Barium Stannate in Barium Titanate, Sov. Phys.— Tech. Phys. (Engl. Transl., 24, 8, pp. 1375-1386, (1954)

[10]

Smolensky G.A., Physical Phenomena in Ferroelectrics with Diffuse Phase Transitions, J. Phys. Soc. Jpn., Suppl., 28, pp. 26-28, (1970)

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