SYNTHESES AND STRUCTURES OF DICYANOBIS (OXAZOLIDIN-2-YLIDENE)PALLADIUM(II) AND PLATINUM(II) COMPLEXES

被引：30
作者：
KERNBACH, U [1 ]
FEHLHAMMER, WP [1 ]
机构：
[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,D-14195 BERLIN,GERMANY
来源：
INORGANICA CHIMICA ACTA | 1995年 / 235卷 / 1-2期
关键词：
CRYSTAL STRUCTURES; PALLADIUM COMPLEXES; PLATINUM COMPLEXES; CARBENE COMPLEXES;
D O I：
10.1016/0020-1693(95)90071-D
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(2-Trimethylsiloxy)ethyl isocyanide reacts with Pd(CN)(2) and Pt(CN)(2) to give trans-[Pd(CN)(2)(CN(H)CH2CH2O)(2)] (1), trans-[Pt(CN)(2)(CN(H)CH2CH2O)(2)] (2) and cis-[Pt(CN)(2)(CN(H)CH2CH2O)(2)] (3), respectively. Complexes 1-3 have been characterized by crystal structure determinations. In the cis compound 3, the carbene ligands are linked by NH ... O hydrogen bonds. A measured Pt ... Pt distance of 3.2828(6) Angstrom in this crystal structure indicates a weak Pt ... Pt interaction.
引用
收藏
页码：299 / 305
页数：7
相关论文
共 50 条
[31]   Nickel(II), palladium(II), platinum(II) and platinum(IV) complexes of cis-1,2-bis(diphenylphosphino)ethene and nitrogen-containing heterocycles or sulfur ligands [J].
Oberhauser, W ;
Bachmann, C ;
Stampfl, T ;
Haid, R ;
Langes, C ;
Rieder, A ;
Bruggeller, P .
INORGANICA CHIMICA ACTA, 1998, 274 (02) :143-154
[32]   Activity of phosphino palladium(II) and platinum(II) complexes against HIV-1 and Mycobacterium tuberculosis [J].
Ntombenhle H. Gama ;
Afag Y. F. Elkhadir ;
Bhavna G. Gordhan ;
Bavesh D. Kana ;
James Darkwa ;
Debra Meyer .
BioMetals, 2016, 29 :637-650
[33]   Syntheses, crystal structure and spectroscopic characterization of new platinum(II) dithiocarbimato complexes [J].
Amim, Raquel S. ;
Oliveira, Marcelo R. L. ;
Perpetuo, Genivaldo J. ;
Janczak, Jan ;
Miranda, Liany D. L. ;
Rubinger, Mayura M. M. .
POLYHEDRON, 2008, 27 (07) :1891-1897
[34]   (Ferrocenylpyrazolyl) palladium(II) complexes: Syntheses, characterization and rearrangement in solution [J].
Obuah, Collins ;
Darkwa, James .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 802 :39-48
[35]   Alternative syntheses and reactivity of platinum(II) terpyridyl acetonitrile complexes [J].
Pappenfus, Ted M. ;
Burney, Jason R. ;
McGee, Kari A. ;
Lee, Garett G. W. ;
Jarvis, Larissa R. ;
Ekerholm, Daniel P. ;
Farah, Mohamed ;
Smith, Lisa I. ;
Hinkle, Lindsay M. ;
Mann, Kent R. .
INORGANICA CHIMICA ACTA, 2010, 363 (13) :3214-3221
[36]   Palladium(II) and platinum(II) complexes of ((2-pyridyl)pyrazol-1-ylmethyl) benzoic acids: Synthesis, Solid state characterisation and biological cytotoxicity [J].
McKay, Aidan P. ;
Lo, Warrick K. C. ;
Preston, Dan ;
Giles, Gregory I. ;
Crowley, James D. ;
Barnsley, Jonathan E. ;
Gordon, Keith C. ;
McMorran, David A. .
INORGANICA CHIMICA ACTA, 2016, 446 :41-53
[37]   Synthesis and structure of platinum(II)- and palladium(II)-phosphorin complexes in solid and solution state [J].
Shiotsuka, Michito ;
Tanamachi, Takahiro ;
Urakawa, Tsuyoshi ;
Matsuda, Yoshihisa .
JOURNAL OF MOLECULAR STRUCTURE, 2006, 794 (1-3) :215-220
[38]   Heterobimetallic platinum(II)-palladium(II) complexes bridged by fluorobenzenethiolates. Structure and equilibria [J].
Rivera, Guillermina ;
Bernes, Sylvain ;
Rodriguez de Barbarin, Cecilia ;
Torrens, Hugo .
INORGANICA CHIMICA ACTA, 2009, 362 (14) :5122-5125
[39]   Neutral bis(carbene) platinum(II) complexes [J].
Zhang, SW ;
Ishii, R ;
Motoori, F ;
Tanaka, T ;
Takai, Y ;
Sawada, M ;
Takahashi, S .
INORGANICA CHIMICA ACTA, 1997, 265 (1-2) :75-82
[40]   Structural and spectroscopic trends in mononuclear arylchalcogenolato-palladium(II) and -platinum(II) complexes:: Crystal structures of [M(TeAr)2(dppe)] {M = palladium, platinum;: Ar = phenyl, 2-thienyl;: dppe=1,2-bis(diphenylphosphino)ethane} [J].
Risto, Maarit ;
Jahr, Esther M. ;
Hannu-Kuure, Mija S. ;
Oilunkaniemi, Raija ;
Laitinen, Risto S. .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (11) :2193-2204
12345