REACTIONS OF DICHLOROMETHANE WITH THIOANIONS .1. PREPARATION OF BIS(N,N-DIALKYLTHIOCARBAMOYLTHIO)METHANES

被引：4
|
作者：
CESPEDES, C
VEGA, JC
机构：
[1] Facultad de Química, Pontificia Universidad Católica de Chile, Correo 22, Santiago
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 90卷 / 1-4期
关键词：
THIOANIONS; DICHLOROMETHANE; PHASE TRANSFER CATALYST; IR SPECTRA;
D O I：
10.1080/10426509408016397
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparation of some bis(N,N-dialkylthiocarbamoylthio)methanes, mainly published in the patent literature, is described. The method is based on the reaction of sodium N,N-dialkyldithiocarbamates in water with dichloromethane catalyzed by poly(ethylene glycol) 1,500. The yields are 50-80%.
引用
收藏
页码：155 / 158
页数：4
相关论文
共 50 条
  • [1] Reactions of dichloromethane with thioanions .3. Preparation and aminolysis of bis(alkoxythiocarbonylthio)methanes
    Benavente, C
    Diaz, P
    Vega, JC
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 116 : 49 - 56
  • [2] 4-(N,N-Dialkylthiocarbamoylthio)-5-nitropyrimidines as new potential nitric oxide donors
    O. B. Ryabova
    E. Yu. Khmel’nitskaya
    V. A. Makarov
    L. M. Alekseeva
    N. B. Grigor’ev
    V. G. Granik
    Russian Chemical Bulletin, 2005, 54 : 2873 - 2879
  • [3] 4-(N,N-dialkylthiocarbamoylthio)-5-nitropyrimidines as new potential nitric oxide donors
    Ryabova, O. B.
    Khmel'nitskaya, E. Yu.
    Makarov, V. A.
    Alekseeva, L. M.
    Grigor'ev, N. B.
    Granik, V. G.
    RUSSIAN CHEMICAL BULLETIN, 2005, 54 (12) : 2873 - 2879
  • [4] PREPARATION AND REACTIONS OF N,N-BIS(HALOMETHYL)CARBOXAMIDES
    BOHME, H
    DENIS, JP
    DRECHSLER, HJ
    LIEBIGS ANNALEN DER CHEMIE, 1979, (10): : 1447 - 1455
  • [5] The reaction of N-methyl-N,N-bis(silatranylmethyl)amine with dichloromethane
    Lazareva, N. F.
    Lazarev, I. M.
    Dianova, N. G.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (10) : 2235 - 2236
  • [6] The reaction of N-methyl-N,N-bis(silatranylmethyl)amine with dichloromethane
    N. F. Lazareva
    I. M. Lazarev
    N. G. Dianova
    Russian Chemical Bulletin, 2008, 57 : 2235 - 2236
  • [7] N-ETHYLBENZISOXAZOLIUM CATION .1. PREPARATION AND REACTIONS WITH NUCLEOPHILIC SPECIES
    KEMP, DS
    WOODWARD, RB
    TETRAHEDRON, 1965, 21 (11) : 3019 - &
  • [8] Synthesis and reactions of N,N-bis[1-(trimethylsiloxy)alkyl]formamides: Preparation of (+/-)-argemonine and (+/-)-norargemonine
    Johnson, AP
    Luke, RWA
    Singh, G
    Boa, AN
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (09): : 907 - 913
  • [9] METAL NITRIDES IN ORGANIC REACTIONS .1. REACTIONS OF LITHIUM NITRIDE WITH ACID CHLORIDES . PREPARATION OF N,N-DIACYLAMIDES
    BALDWIN, FP
    BLANCHAR.EJ
    KOENIG, PE
    JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (03): : 671 - &
  • [10] PREPARATION AND CRYSTAL-STRUCTURE OF DIOXOTETRACHLORO(N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)BIS(TRIPHENYLPHOSPHINE)DIRHENIUM(V) DICHLOROMETHANE SOLVATE
    BOMBIERI, G
    MAZZI, U
    GILLI, G
    HERNANDEZCANO, F
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 159 (01) : 53 - 62
12345