KINETICS OF DESOLVATION OF INCLUSION-COMPOUNDS OF 9,10-DERIVATIVES OF TRANS-9,10-DIHYDROXY-9,10-DIHYDROANTHRACENE WITH BENZENE

被引：10

作者：

BARBOUR, LJ

CAIRA, MR

COETZEE, A

NASSIMBENI, LR

机构：

[1] UNIV MISSOURI,DEPT CHEM,COLUMBIA,MO 65211

[2] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1995年 / 07期

关键词：

D O I：

10.1039/p29950001345

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structures of the inclusion compounds of trans-9,10-dihydroxy-9,10-di-p-tert-butylphenyl-9, 10-dihydro-anthracene (DDTBDA) and trans-9,10-dihydroxy-9, 10-di-alpha-naphthyl-9,10-dihydroanthracene (DDNDA) with benzene, with host:guest ratios of 1:3 and 1:1, respectively, have been elucidated. Their isothermal kinetics of desolvation have been studied. DDTBDA . 3benzene desolvates in a single deceleratory step following the first-order kinetic model. The cl us. time curves for the desolvation of DDNDA . benzene are of truncated sigmoidal shape and are best described by the Prout-Tomkins model.

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页码：1345 / 1349

页数：5

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