ON THE JAHN-TELLER COUPLING OF AN ORBITAL TRIPLET WITH A VIBRATIONAL DOUBLET

被引：1

作者：

GHELICHKHANI, E

GRANT, ER

机构：

[1] Department of Chemistry, Purdue University, West Lafayette

来源：

CHEMICAL PHYSICS | 1991年 / 153卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(91)90013-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We explore the problem of an orbitally triple degenerate electronic state coupled with a doubly degenerate vibrational mode, for a molecule within the T(d) rigid geometrical point group, using exact as well as numerical methods. Franck-Condon overlap integrals are worked out and are displayed as a function of linear coupling parameter. The effect of inclusion of quadratic coupling terms on the eigenvalue and intensity distribution are compared with the linear case.

引用

页码：133 / 140

页数：8