ANHARMONICITY OF THE OH ... O HYDROGEN-BOND IN LIQUID WATER

被引：4
|
作者：
IIJIMA, T
机构：
[1] Department of Chemistry, Gakushuin University, Toshimaku, Tokyo
来源：
CHEMICAL PHYSICS LETTERS | 1994年 / 217卷 / 5-6期
关键词：
D O I：
10.1016/0009-2614(93)E1428-J
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The X-ray scattering intensities of liquid water observed by Narten and Levy have been reanalyzed, especially in the region 7-16 Angstrom(-1) of the scattering parameter. The intensities in this region are accounted for as an interference pattern due to the OH...O hydrogen bond with anharmonicity. The Morse anharmonicity parameter is estimated to be 1.9 +/- 0.8 Angstrom(-1), which is nearly equal to those observed for ordinary chemical bonds. The distance and the root-mean-square amplitude are determined as 2.91 +/- 0.02 Angstrom and 0.17 +/- 0.01 Angstrom, respectively.
引用
收藏
页码：503 / 506
页数：4
相关论文
共 50 条
  • [1] The OH stretch vibration of liquid water reveals hydrogen-bond clusters
    Garrett-Roe, Sean
    Hamm, Peter
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (37) : 11263 - 11266
  • [2] Hydrogen-bond kinetics in liquid water
    Luzar, A
    Chandler, D
    NATURE, 1996, 379 (6560) : 55 - 57
  • [3] Hydrogen-bond kinetics in liquid water
    Nature, 6560 (55):
  • [4] HYDROGEN-BOND PATTERNS IN LIQUID WATER
    Rahman, A
    Stillinger, FH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (24) : 7943 - 7948
  • [5] Dynamics of the hydrogen-bond in liquid water
    Gale, GM
    Gallot, G
    Hache, F
    Lascoux, N
    ULTRAFAST PHENOMENA XI, 1998, 63 : 574 - 576
  • [6] Hydrogen-bond structure and anharmonicity in croconic acid
    Mukhopadhyay, Sanghamitra
    Gutmann, Matthias
    Fernandez-Alonso, Felix
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (47) : 26234 - 26239
  • [7] INSTABILITIES OF HYDROGEN-BOND NETWORK IN LIQUID WATER
    SASAI, M
    JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (10): : 7329 - 7341
  • [8] Refinements on solvation continuum models: Hydrogen-bond effects on the OH stretch in liquid water and methanol
    Cappelli, C
    Mennucci, B
    da Silva, CO
    Tomasi, J
    JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (12): : 5382 - 5392
  • [9] Insights on Hydrogen-Bond Lifetimes in Liquid and Supercooled Water
    Martiniano, H. F. M. C.
    Galamba, N.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2013, 117 (50): : 16188 - 16195
  • [10] Topological properties of the hydrogen-bond network in liquid water
    Bergman, DL
    CHEMICAL PHYSICS, 2000, 253 (2-3) : 267 - 282
12345