NON-STEADY-STATE MODEL FOR KINETICS OF FREE-RADICAL POLYMERIZATION .2. REDOX INITIATION

被引：2

作者：

YAN, DY ^{[1
]}

LIN, JM ^{[1
]}

YUAN, CM ^{[1
]}

FENG, J ^{[1
]}

机构：

[1] SHANGHAI JIAO TONG UNIV,DEPT APPL CHEM,SHANGHAI 200030,PEOPLES R CHINA

来源：

POLYMER INTERNATIONAL | 1992年 / 28卷 / 02期

关键词：

RADICAL POLYMERIZATION; REDOX INITIATION; KINETICS OF POLYMERIZATION; NON-STEADY-STATE MODEL; MOLECULAR WEIGHT DISTRIBUTION; MOLECULAR PARAMETERS;

D O I：

10.1002/pi.4990280204

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This work deals with the non-steady-state kinetics of free radical polymerization with redox initiation. Rigorous expressions for the radical concentration, monomer conversion, molecular size distribution function, and number-average and weight-average molecular weights, etc., were derived. The molecular parameters of the resulting polymer were evaluated in relation to the polymerization conditions.

引用

页码：115 / 121

页数：7

共 36 条

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