NON-STEADY-STATE MODEL FOR KINETICS OF FREE-RADICAL POLYMERIZATION .2. REDOX INITIATION

被引：2

作者：

YAN, DY ^{[1
]}

LIN, JM ^{[1
]}

YUAN, CM ^{[1
]}

FENG, J ^{[1
]}

机构：

[1] SHANGHAI JIAO TONG UNIV,DEPT APPL CHEM,SHANGHAI 200030,PEOPLES R CHINA

来源：

POLYMER INTERNATIONAL | 1992年 / 28卷 / 02期

关键词：

RADICAL POLYMERIZATION; REDOX INITIATION; KINETICS OF POLYMERIZATION; NON-STEADY-STATE MODEL; MOLECULAR WEIGHT DISTRIBUTION; MOLECULAR PARAMETERS;

D O I：

10.1002/pi.4990280204

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This work deals with the non-steady-state kinetics of free radical polymerization with redox initiation. Rigorous expressions for the radical concentration, monomer conversion, molecular size distribution function, and number-average and weight-average molecular weights, etc., were derived. The molecular parameters of the resulting polymer were evaluated in relation to the polymerization conditions.

引用

页码：115 / 121

页数：7

共 12 条

[1]

BULLOCK AT, 1972, CHEM ZVESTI, V26, P193

[2]

HU QS, 1991, J MACROMOL SCI CHE A, V28, P503

[3]

HU QS, 1988, NATIONAL S POLYM SYN

[4]

TANG AC, 1962, SCI SINICA, V11, P605

[5]

TOMPA H, 1976, COMPREHENSIVE CHEM A, V14, pCH7

[6]

YAN D, 1987, INT S GENOVA, P97

[7] INFLUENCE OF TERMINATION AND TRANSFER ON MOLECULAR-WEIGHT DISTRIBUTION OF POLYMERS .1. DISPROPORTIONATION AND COMBINATION [J].

YAN, DY ;

CAI, GF .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1986, A23 (01) :37-57

[8]

YAN DY, 1987, MAKROMOL CHEM, V188, P333

[9]

YAN DY, 1986, MAKROMOL CHEM, V187, P2179

[10]

YUAN CM, 1987, MAKROMOL CHEM, V188, P341

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