Diglycolamide-Based Solvent Systems in Room Temperature Ionic Liquids for Actinide Ion Extraction: A Review

被引：48
|
作者：
Mohapatra, Prasanta Kumar [1 ]
机构：
[1] Bhabha Atom Res Ctr, Radiochem Div, Bombay 400085, Maharashtra, India
来源：
CHEMICAL PRODUCT AND PROCESS MODELING | 2015年 / 10卷 / 02期
关键词：
diglycolamides; ionic liquids; actinides; solvent extraction;
D O I：
10.1515/cppm-2014-0030
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
This review article gives a comprehensive account of the extraction of actinide ions using room temperature ionic liquid-based solvent systems containing diglycolamide (DGA) or functionalized DGA extractants. These extractants include multiple DGA-functionalized ligands such as tripodal DGA (T-DGA) and DGA-functionalized calix [4]arenes (C4DGA). Apart from metal ion extraction behaviour, other important features of the ionic liquid-based solvent systems such as separation behaviour, luminescence spectroscopic results, thermodynamics of extraction and radiolytic stability of the ionic liquid-based solvents are also reviewed. Results from studies on DGA-functionalized task-specific ionic liquids (TSIL) are also included in this review article.
引用
收藏
页码：135 / 145
页数：11
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