THE BREMSSTRAHLUNG ISOCHROMAT SPECTRA OF D(0) TRANSITION-METAL OXIDES

被引:9
|
作者
SORIANO, L
ABBATE, M
ALDERS, D
SANZ, JM
机构
[1] CATHOLIC UNIV NIJMEGEN,6525 ED NIJMEGEN,NETHERLANDS
[2] UNIV GRONINGEN,CTR MAT SCI & ENGN,9747 AG GRONINGEN,NETHERLANDS
关键词
THIN FILMS; INSULATORS; ELECTRONIC BAND STRUCTURE; CRYSTAL AND LIGAND FIELDS; X-RAY AND GAMMA-RAY SPECTROSCOPIES;
D O I
10.1016/0038-1098(94)90372-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We present and discuss the bremsstrahlung isochromat spectra (BIS) of four d0 transition-metal oxides, namely ZrO2, HfO2, Nb2O5, and Ta2O5. The spectra are related to the density of unoccupied states in the conduction band. They give directly the magnitude of the crystal-field splitting and the dispersion of the metal-d bands. The trends observed in the spectra are discussed and compared to those found in the O 1s x-ray absorption spectra (XAS) of the same materials.
引用
收藏
页码:551 / 554
页数:4
相关论文
共 50 条
  • [1] Systematic Analysis of ARPES Spectra of Transition-Metal Oxides: Nature of Effective d Band
    Wadati, Hiroki
    Chikamatsu, Akira
    Takizawa, Masaru
    Kumigashira, Hiroshi
    Yoshida, Teppei
    Mizokawa, Takashi
    Fujimori, Atsushi
    Oshima, Masaharu
    Hamada, Noriaki
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2009, 78 (09)
  • [2] Empirical correction for PM7 band gaps of transition-metal oxides
    Liu, Xiang
    Sohlberg, Karl
    JOURNAL OF MOLECULAR MODELING, 2016, 22 (01) : 1 - 10
  • [3] EQUATION OF MOTION METHOD FOR THE ELECTRONIC-STRUCTURE OF DISORDERED TRANSITION-METAL OXIDES
    MICHALEWICZ, MT
    SHORE, HB
    TIT, N
    HALLEY, JW
    COMPUTER PHYSICS COMMUNICATIONS, 1992, 71 (03) : 222 - 234
  • [4] Semiconducting transition-metal oxides based on d5 cations: Theory for MnO and Fe2O3
    Peng, Haowei
    Lany, Stephan
    PHYSICAL REVIEW B, 2012, 85 (20)
  • [5] Building Brain-Inspired Logic Circuits from Dynamically Switchable Transition-Metal Oxides
    Andrews, Justin L.
    Santos, David A.
    Meyyappan, M.
    Williams, R. Stanley
    Banerjee, Sarbajit
    TRENDS IN CHEMISTRY, 2019, 1 (08): : 711 - 726
  • [6] Alloying-induced topological transition in 2D transition-metal dichalcogenide semiconductors
    Ouyang, Liying
    Hu, Ge
    Qi, Can
    Hu, Jun
    APPLIED PHYSICS EXPRESS, 2019, 12 (04)
  • [7] Transition-Metal Oxides Anchored on Nitrogen-Enriched Carbon Ribbons for High-Performance Pseudocapacitors
    Pang, Yuanchao
    Zhang, Shuyang
    Chen, Sheng
    Liang, Jin
    Li, Mingyan
    Ding, Dawei
    Ding, Shujiang
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (60) : 16104 - 16112
  • [8] Unit-cell-level assembly of metastable transition-metal oxides by pulsed-laser deposition
    Yan, Lei
    Niu, Hongjun
    Bridges, Craig A.
    Marshall, Paul A.
    Hadermann, Joke
    van Tendeloo, Gustaav
    Chalker, Paul R.
    Rosseinsky, Matthew J.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (24) : 4539 - 4542
  • [9] Electroplating lithium transition metal oxides
    Zhang, Huigang
    Ning, Hailong
    Busbee, John
    Shen, Zihan
    Kiggins, Chadd
    Hua, Yuyan
    Eaves, Janna
    Davis, Jerome, III
    Shi, Tan
    Shao, Yu-Tsun
    Zuo, Jian-Min
    Hong, Xuhao
    Chan, Yanbin
    Wang, Shuangbao
    Wang, Peng
    Sun, Pengcheng
    Xu, Sheng
    Liu, Jinyun
    Braun, Paul V.
    SCIENCE ADVANCES, 2017, 3 (05):
  • [10] 2D Metallic Transition-Metal Dichalcogenides: Structures, Synthesis, Properties, and Applications
    Zhao, Bei
    Shen, Dingyi
    Zhang, Zucheng
    Lu, Ping
    Hossain, Mongur
    Li, Jia
    Li, Bo
    Duan, Xidong
    ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (48)