SYNTHESIS OF THE NEW TRIPODAL LIGAND TRIS-[3-(2'-PYRIDYL)PYRAZOL-1-YL]HYDROBORATE, AND THE CRYSTAL-STRUCTURE OF ITS EUROPIUM(III) COMPLEX

被引:129
作者
AMOROSO, AJ [1 ]
THOMPSON, AMC [1 ]
JEFFERY, JC [1 ]
JONES, PL [1 ]
MCCLEVERTY, JA [1 ]
WARD, MD [1 ]
机构
[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND
关键词
D O I
10.1039/c39940002751
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new tripodal ligand tris-[3-(2'-pyridyl)pyrazol-1-yl]hydroborate (L(-)), comprising three N,N-bidentate chelating arms linked by the epical boron atom, has been synthesized; the crystal structure of [EuL(MeOH)(2)F][PF6] reveals the nine-coordinate metal lying within the hexadentate ligand cavity.
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页码:2751 / 2752
页数:2
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