PREPARATION AND VIBRATIONAL SPECTROSCOPY OF DI-N-BUTYL PHOSPHATE COMPLEXES OF ZIRCONIUM NITRATE

被引：8

作者：

EDWARDS, HGM ^{[1
]}

HUGHES, MA ^{[1
]}

SMITH, DN ^{[1
]}

COURTNEY, B ^{[1
]}

机构：

[1] BRITISH NUCL FUELS PLC,THORP DIV,SEASCALE CA20 1PG,ENGLAND

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 351卷

关键词：

D O I：

10.1016/0022-2860(94)08486-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational spectra of the complexes Zr(NO3), (DBP)(2) and Zr(NO3)(2)(DBP)(2)(HDBP)(4) have been characterised, with the provision of Raman spectroscopic data for the first time. Several inconsistencies in the literature for the infrared spectra of these compounds have been resolved and from Raman polarisation data the mode of coordination of the nitrate ligand in the Zr(NO3)(2)(DBP)(2)(HDBP)(4) complex is suggested to be monodentate.

引用

页码：65 / 76

页数：12

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