RECENT PROGRESS USING CHIRAL FORMAMIDINES IN ASYMMETRIC SYNTHESES

被引：98

作者：

MEYERS, AI

机构：

[1] Department of Chemistry, Colorado State University, Fort Collins

来源：

TETRAHEDRON | 1992年 / 48卷 / 13期

关键词：

D O I：

10.1016/S0040-4020(01)88523-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ability to generate a carbanion next to nitrogen in a chiral environment has led to a number of useful asymmetric routes to alkaloids and related substances. Mechanistic studies have been conducted to understand the nature of these alkylations.

引用

页码：2589 / 2612

页数：24

共 40 条

[31]

MEYERS AI, 1991, IN PRESS TETRAHEDRON

[32] CHIRAL DIPOLE-STABILIZED ANIONS - EXPERIMENT AND THEORY IN BENZYLIC AND ALLYLIC SYSTEMS - STEREOSELECTIVE DEPROTONATIONS, PYRAMIDAL INVERSIONS, AND STEREOSELECTIVE ALKYLATIONS OF LITHIATED (TETRAHYDROISOQUINOLYL)OXAZOLINES [J].

REIN, K ;

GOICOECHEAPAPPAS, M ;

ANKLEKAR, TV ;

HART, GC ;

SMITH, GA ;

GAWLEY, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) :2211-2217

[33] INDOLE ALKALOIDS - ENANTIOSELECTIVE SYNTHESIS OF (-)-ALLOYOHIMBANE BY A CHEMOENZYMATIC APPROACH [J].

RIVA, R ;

BANFI, L ;

DANIELI, B ;

GUANTI, G ;

LESMA, G ;

PALMISANO, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :299-300

[34] ALKYLATION OF THE ISOQUINOLINE SKELETON IN THE 1-POSITION - LITHIATED 2-PIVALOYL AND 2-BIS(DIMETHYLAMINO)-PHOSPHINOYL-1,2,3,4-TETRAHYDROISOQUINOLINES [J].

SEEBACH, D ;

LOHMANN, JJ ;

SYFRIG, MA ;

YOSHIFUJI, M .

TETRAHEDRON, 1983, 39 (12) :1963-1974

[35]

SEEBACH D, 1975, ANGEW CHEM INT EDIT, V14, P15, DOI 10.1002/anie.197500151

[36]

Szantay C., 1986, ALKALOIDS, V27, P131

[37] SILICON-MEDIATED ISOQUINOLINE ALKALOID SYNTHESIS - A NEW ROUTE TO THE DIBENZOPYRROCOLINE ALKALOID (+/-)-CRYPTAUSTOLINE [J].

TAKANO, S ;

SATOH, S ;

OGASAWARA, K .

HETEROCYCLES, 1987, 26 (06) :1483-1485

[38] STEREOCHEMISTRY OF THE DIBENZOPYRROCOLINE ALKALOIDS CRYPTAUSTOLINE AND CRYPTOWOLINE [J].

TAKANO, S ;

SATOH, S ;

OSHIMA, Y ;

OGASAWARA, K .

HETEROCYCLES, 1987, 26 (06) :1487-1489

[39] ASYMMETRIC TOTAL SYNTHESIS OF DIBENZOCYCLOOCTADIENE LIGNANS (-)-SCHIZANDRIN AND (-)-ISOSCHIZANDRIN - STRUCTURE REVISION OF (+)-ISOSCHIZANDRIN [J].

WARSHAWSKY, AM ;

MEYERS, AI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (22) :8090-8099

[40] A NOVEL TOTAL SYNTHESIS OF (+)-CRYPTAUSTOLINE, A DIBENZOPYRROCOLINE ALKALOID [J].

YASUDA, S ;

HIRASAWA, T ;

YOSHIDA, S ;

HANAOKA, M .

CHEMICAL & PHARMACEUTICAL BULLETIN, 1989, 37 (06) :1682-1683

← 1 2 3 4 →