THE FOURIER-TRANSFORM RAMAN-SPECTRA OF A SERIES OF PLATINUM(II), PALLADIUM(II) AND GOLD(III) SQUARE-PLANAR COMPLEXES

被引：42

作者：

DEGEN, IA ^{[1
]}

ROWLANDS, AJ ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 9-10期

关键词：

D O I：

10.1016/0584-8539(91)80213-3

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Fourier transform Raman spectra of solid samples and some D2O solutions, of complexes of formula KnMX4, M = Pt(II), Pd(II), and Au(III); X = Cl and Br are reported. It was found that the spectra of the tetrabromides contain more bands than the corresponding tetrachlorides; this indication that the two halides have different crystal structures is discussed. Fourier transform Raman spectra of M(NH3)4Cl2, M = Pt(II), and Pd(II), trans- and cis-Pt(NH3)2Cl2 (i.e. the pharmaceutical product "cis-platin"), and trans-Pd(NH3)2X2, X = Cl and Br are also reported here and the significance of the spectra discussed. Although many of these spectra have been reported earlier the quality of the new Fourier transform data is superior to that in the literature.

引用

页码：1263 / 1268

页数：6

共 24 条

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