ANALYSIS OF GAS SOLUBILITIES IN ALKANES USING A HARD-SPHERE EQUATION OF STATE

被引：0
|
作者：
SADUS, RJ
YOUNG, CL
机构：
[1] UNIV MELBOURNE,DEPT PHYS CHEM,PARKVILLE,VIC 3052,AUSTRALIA
[2] SWINBURNE INST TECHNOL,CTR APPL COLLOID SCI,HAWTHORN,VIC 3122,AUSTRALIA
来源：
FLUID PHASE EQUILIBRIA | 1991年 / 63卷 / 1-2期
关键词：
D O I：
10.1016/0378-3812(91)80022-N
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The one fluid model together with the hard sphere equation of state due to Guggenheim was used to calculate the solubility of argon, xenon, krypton, nitrogen, carbon monoxide, carbon tetrafluoride, sulphur hexafluoride, methane, ethane and propane in various alkanes (C5-C30) at a partial pressure of 1 atm and typically between 280 and 350 K. The agreement between theory and experiment is generally quite good. The xi values obtained from the analysis reflect the strength of intermolecular interaction between unlike molecules.
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页码：91 / 99
页数：9
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