HYDROGEN-PRODUCTION FROM 2-PROPANOL AS A KEY REACTION FOR A CHEMICAL HEAT-PUMP WITH REACTION COUPLE OF 2-PROPANOL DEHYDROGENATION ACETONE HYDROGENATION

被引：26
作者：
SAITO, Y
YAMASHITA, M
ITO, E
MENG, N
机构：
[1] Department of Industrial Chemistry, Faculty of Engineering, University of Tokyo, Bunkyo-ku, Tokyo, 113
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 1994年 / 19卷 / 03期
关键词：
D O I：
10.1016/0360-3199(94)90089-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogen production from 2-propanol under boiling and refluxing conditions (80-degrees-C) constitutes a chemical heat pump system, by coupling with the separation procedure of 2-propanol from acetone and hydrogen at ambient temperature and the exothermic reverse reaction at high temperature (200-degrees-C). Chemical conversion and storage of low-quality heat are advantageous for solar heat utilization. The role of catalysis for the endothermic 2-propanol dehydrogenation is especially important. The high activity of Ru and the low product retardation over Pt were noteworthy. A composite Ru-Pt catalyst and its surface modification with Pt(acaC)2 or Pd(acaC)2 exhibited activity enhancements.
引用
收藏
页码：223 / 226
页数：4
相关论文
共 32 条
[1]   THE PHOTOCATALYTIC DEHYDROGENATION OF 2-PROPANOL BY USING RHC1(PPH3)3 [J].
ARAKAWA, H ;
SUGI, Y .
CHEMISTRY LETTERS, 1981, (09) :1323-1326
[2]   APPLICATIONS OF LIGHT-INDUCED ELECTRON-TRANSFER AND HYDROGEN-ABSTRACTION PROCESSES - PHOTOELECTROCHEMICAL PRODUCTION OF HYDROGEN FROM REDUCING RADICALS [J].
CHANDRASEKARAN, K ;
WHITTEN, DG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (15) :5119-5120
[3]   HYDRIDE TRANSFER REACTIONS CATALYSED BY RHODIUM-TIN COMPLEXES [J].
CHARMAN, HB .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (04) :584-&
[4]  
CLAES F, 1963, B SOC CHIM FRANCE 5, V25, P1167
[5]   COMPLEXES OF PLATINUM METALS .7. HOMOGENEOUS RUTHENIUM AND OSMIUM CATALYSTS FOR DEHYDROGENATION OF PRIMARY AND SECONDARY ALCOHOLS [J].
DOBSON, A ;
ROBINSON, SD .
INORGANIC CHEMISTRY, 1977, 16 (01) :137-142
[6]   DEHYDROGENATION OF SECONDARY-ALCOHOLS TO KETONES PROMOTED BY RHODIUM AND IRIDIUM CATALYSTS AND ALKALI [J].
FRAGALE, C ;
ROSSI, M ;
GARGANO, M .
JOURNAL OF MOLECULAR CATALYSIS, 1979, 5 (01) :65-73
[7]   CHEMICAL-REACTION CYCLES FOR RECOVERY OF LOW-LEVEL THERMAL-ENERGY [J].
FUJII, S ;
KAMEYAMA, H ;
YOSHIDA, K ;
KUNII, D .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1977, 10 (03) :224-228
[8]   PHOTOCATALYTIC DEHYDROGENATION OF PROPAN-2-OL USING RHODIUM BASED CATALYSTS [J].
GRIGGS, CG ;
SMITH, DJH .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 273 (01) :105-109
[9]   A COMPOSITE RU-PT CATALYST FOR 2-PROPANOL DEHYDROGENATION ADOPTABLE TO THE CHEMICAL HEAT-PUMP SYSTEM [J].
ITO, E ;
YAMASHITA, M ;
HAGIWARA, S ;
SAITO, Y .
CHEMISTRY LETTERS, 1991, (03) :351-354
[10]   DEHYDROGENATION OF ALCOHOLS AND HYDROGENATION OF ALDEHYDES USING HOMOGENEOUS RUTHENIUM CATALYSTS [J].
JUNG, CW ;
GARROU, PE .
ORGANOMETALLICS, 1982, 1 (04) :658-666
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