INCOMPLETE COORDINATION TO RHENIUM(V) BY A FACULTATIVE QUINQUEDENTATE LIGAND - THE X-RAY CRYSTAL-STRUCTURE OF [REO(OME)(2'-(NC4H3-2-CH=N(CH2)3NME(CH2)3CH=N-)C4H3NH)]PF6

被引：4

作者：

BANBERY, HJ ^{[1
]}

MCQUILLAN, FS ^{[1
]}

HAMOR, TA ^{[1
]}

JONES, CJ ^{[1
]}

MCCLEVERTY, JA ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,DEPT CHEM,POB 363,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)86242-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Bu4N[ReOCl4(H2O)] and the Schiff base ligand {HNC4H3- 2-CHN(CH2)3}2NMe in methanol affords the cationic complex [ReO(OMe){2′-(NC4H3- 2-CHN(CH2)3NMe(CH2)3CHN)C4H3NH}]PF6. An X-ray diffraction study of this complex reveals a six coordinate, nearly octahedral rhenium(V) centre coordinated to only four nitrogen donor atoms from the quinquedentate ligand. One terminal pyrrolyl group remains protonated and uncoordinated. The remaining two coordination sites are occupied by the mutually trans oxo and methoxide ligands. © 1990.

引用

页码：615 / 618

页数：4

共 14 条

[1] CAMBRIDGE CRYSTALLOGRAPHIC DATA CENTER - COMPUTER-BASED SEARCH, RETRIEVAL, ANALYSIS AND DISPLAY OF INFORMATION [J].

ALLEN, FH ;

BELLARD, S ;

BRICE, MD ;

CARTWRIGHT, BA ;

DOUBLEDAY, A ;

HIGGS, H ;

HUMMELINK, T ;

HUMMELINKPETERS, BG ;

KENNARD, O ;

MOTHERWELL, WDS ;

RODGERS, JR ;

WATSON, DG .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (OCT) :2331-2339

[2]

[Anonymous], 1978, INFRARED RAMAN SPECT

[3] THE SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF RHENIUM(V) COMPLEXES CONTAINING FACULTATIVE PENTADENTATE LIGANDS [J].

BANBERY, HJ ;

MCQUILLAN, F ;

HAMOR, TA ;

JONES, CJ ;

MCCLEVERTY, JA .

POLYHEDRON, 1989, 8 (04) :559-561

[4] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [REO(CL)((2-OC6H4CH=NCH2-CH2OCH2)2)], AN EXAMPLE OF 4-CO-ORDINATION BY A POTENTIALLY SEXIDENTATE LIGAND [J].

BANBERY, HJ ;

MCQUILLAN, F ;

HAMOR, TA ;

JONES, CJ ;

MCCLEVERTY, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (07) :1405-1407

[5]

BANDOLI G, 1986, TECHNETIUM CHEM NUCL, V2

[6] TRANSITION-METAL SCHIFF BASE COMPLEXES .3. NICKEL COMPLEXES DERIVED FROM PYRROLE-2-CARBALDEHYDE AND ALIPHATIC AND AROMATIC DIAMINES [J].

JONES, CJ ;

MCCLEVER.JA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (08) :1052-&

[7] SCHIFF-BASE COMPLEXES OF RHENIUM(IV) AND RHENIUM(V) [J].

MIDDLETON, AR ;

MASTERS, AF ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (03) :542-546

[8]

MOTHERWELL WDS, 1978, PLUTO PROGRAM PLOTTI

[9] TECHNETIUM(V) AND RHENIUM(V) COMPLEXES WITH SCHIFF-BASE LIGANDS CONTAINING THE ONNNO DONOR ATOM SET - CRYSTAL-STRUCTURE OF [N,N'-3-AZAPENTANE-1,5-DIYLBIS(SALICYLIDENEIMINATO)(3-)-O,O',N,N',N'']-OXOTECHNETIUM(V) [J].

REFOSCO, F ;

TISATO, F ;

MAZZI, U ;

BANDOLI, G ;

NICOLINI, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (03) :611-615

[10] THE SYNTHESIS OF IRON(III) AND COBALT(III) COMPLEXES OF FACULTATIVE HEXADENTATE LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF [FE((NC4H3-2-CH=NCH2CH2NHCH2)2)]PF6 [J].

ROTHIN, AS ;

BANBERY, HJ ;

BERRY, FJ ;

HAMOR, TA ;

JONES, CJ ;

MCCLEVERTY, JA .

POLYHEDRON, 1989, 8 (04) :491-504

← 1 2 →