HYDRIDE TRANSFER BY HYDRIDE TRANSITION-METAL COMPLEXES - IONIC HYDROGENATION OF ALDEHYDES AND KETONES, AND STRUCTURAL CHARACTERIZATION OF AN ALCOHOL COMPLEX

被引：80
|
作者：
SONG, JS
SZALDA, DJ
BULLOCK, RM
LAWRIE, CJC
RODKIN, MA
NORTON, JR
机构：
[1] BROOKHAVEN NATL LAB,DEPT CHEM,UPTON,NY 11973
[2] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523
[3] CUNY BERNARD M BARUCH COLL,NEW YORK,NY 10010
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 09期
关键词：
D O I：
10.1002/anie.199212331
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The rate-determining step in the hydrogenation of aldehydes or ketones by hydrido complexes and acids appears to be the hydride transfer from the complex to the protonated carbonyl compound. The resulting alcohol is initially hound as ligand, as confirmed by an X-ray crystal structure analysis of the alcohol complex 1.
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收藏
页码：1233 / 1235
页数：3
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