A NOVEL REDOX SYSTEM FOR THE PALLADIUM(II)-CATALYZED OXIDATION BASED ON REDOX OF POLYANILINES

被引:58
作者
HIRAO, T
HIGUCHI, M
HATANO, B
IKEDA, I
机构
关键词
D O I
10.1016/0040-4039(95)01143-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A complex system consisting of palladium(ll) acetate and polyaniline derivatives permitted the catalytic Wacker oxidation, indicating that polyanilines serve as a ligand with reversible redox capability under oxygen atmosphere, Substitution on the phenyl ring and protonic acid doping of polyanilines were found to affect the catalytic activity.
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页码:5925 / 5928
页数:4
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