TERPENE AND TERPENE DERIVATIVES .26. FUNCTIONALIZED SILPHIPERFOLENES FROM ARTEMISIA-LACINIATA

被引：13

作者：

WEYERSTAHL, P ^{[1
]}

MARSCHALLWEYERSTAHL, H ^{[1
]}

SCHRODER, M ^{[1
]}

BRENDEL, J ^{[1
]}

KAUL, VK ^{[1
]}

机构：

[1] CENT INST MED & AROMAT PLANTS,SRINAGAR 190005,INDIA

来源：

PHYTOCHEMISTRY | 1991年 / 30卷 / 10期

关键词：

ARTEMISIA-LACINIATA; COMPOSITAE; SILPHIPERFOLENE; SESQUITERPENES;

D O I：

10.1016/0031-9422(91)83207-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Medium polar, high boiling fractions of the essential oil from Artemisia laciniata afforded (3S,4S,7R,9R)-silphiperfol-5-en-3-ol as a major constituent. The structure was elucidated by NMR studies and by identification of its oxidation products. The isomeric alcohol (3S,4S,7S,9R-silphiperfol-5-en-3-ol and the corresponding ketones are minor components, silphiperfol-5-enes, (3R,4S,7R,9R)- and (3R,4S,7S,9R)-silphiperfol-5-en-3-ol, and silphiperfol-6-ene-3,5-dione are trace constituents of the oil.

引用

页码：3349 / 3352

页数：4

共 9 条

[1] NATURALLY-OCCURRING TERPENE DERIVATIVES .286. TRICYCLIC SESQUITERPENES AND FURTHER DITERPENES FROM ESPELETIOPSIS SPECIES [J].