NEW METHODS OF PREPARING F-ALKYL OXIRANES FROM 2-BROMO-2-F-ALKYLETHYL ACETATES AND 2-BROMO-2-F-ALKYLETHANOLS

被引：27

作者：

CHAABOUNI, MM ^{[1
]}

BAKLOUTI, A ^{[1
]}

SZONYI, S ^{[1
]}

CAMBON, A ^{[1
]}

机构：

[1] UNIV NICE,CHIM ORGAN FLUOR LAB,F-06034 NICE,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 46卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)80998-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

F-alkyl oxiranes provide many interesting intermediates. Their synthesis from 2-bromo-2-F-alkylethyl acetates and from 2-bromo-2-F-alkylethanols was improved by two different methods which are very easy to apply. One requires the use of concentrated caustic soda and a phase transfer catalysts; the other one, potassium fluoride in triethylene glycol. © 1990.

引用

页码：307 / 315

页数：9

共 10 条

[1] FLUORIDE-ION AS A BASE IN ORGANIC-SYNTHESIS [J].