APPLICATION OF FLUCTUATION SOLUTION THEORY TO THERMODYNAMIC PROPERTIES OF SOLUTIONS

被引：33
作者：
OCONNELL, JP
机构：
[1] University of Virginia, Charlottesville
来源：
FLUID PHASE EQUILIBRIA | 1995年 / 104卷
关键词：
THEORY; STATISTICAL MECHANICS; THERMODYNAMIC PROPERTIES; SOLUTIONS;
D O I：
10.1016/0378-3812(94)02637-G
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Fluctuation Solution Theory connects certain thermodynamic partial derivatives to integrals of molecular correlation functions from statistical mechanics. This paper describes some applications of this method for correlating and predicting properties of solutions of chemical engineering interest. The method has been used for three kinds of practical systems: A) the densities and compressibilities of liquids; B) the densities and phase equilibria of supercritical substances with liquids; and C) the densities and activities of aqueous electrolytes. The paper illustrates the method for these cases and gives recent results.
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收藏
页码：21 / 39
页数：19
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