EFFECTS OF HEAT-TREATMENT CONDITIONS ON THE CRITICAL CURRENT DENSITIES OF BA2YCU3O7-Y FILMS PREPARED BY THE DIPPING-PYROLYSIS PROCESS

被引:41
作者
KUMAGAI, T [1 ]
MANABE, T [1 ]
KONDO, W [1 ]
MINAMIUE, H [1 ]
MIZUTA, S [1 ]
机构
[1] NIHON KAGAKU SANGYO,TAITO,TOKYO 110,JAPAN
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 1990年 / 29卷 / 06期
关键词
Ba[!sub]2[!/sub] YCu[!sub]3[!/sub]0 [!sub]7[!/sub]-Y superconductor; Bac0[!sub]3[!/sub]-y [!sub]2[!/sub]0 [!sub]3[!/sub]-CuO mixture; Critical current density; Dipping-pyrolysis process; Film; Metal acetylacetonates; Oxygen partial pressure; Reaction;
D O I
10.1143/JJAP.29.L940
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effects of temperature and atmosphere on the BYCO formation reaction of BaCO3, Y2O3 and CuO, prepared by the pyrolysis of metal acetylacetonate solution, were examined by TG-DTA, XRD and resistivity measurement. This reaction was found to proceed readily below 900°C under low oxygen partial pressures. Superconducting Ba2YCu3O7-y films with Tc,zero≅90 K and Jc(77 K)=300–400 A/cm2 were prepared by the dipping-pyrolysis process using the above solution through heat treatments at 820°–880°C under controlled low oxygen partial pressures of ρ(O2)=1×10-3–2×10-4 atm followed by O2 annealing. © 1990 The Japan Society of Applied Physics.
引用
收藏
页码:L940 / L942
页数:3
相关论文
共 3 条
[1]   PREPARATION OF SUPERCONDUCTING YBA2CU3O7-DELTA FILMS BY THE DIPPING-PYROLYSIS PROCESS USING METAL ACETYLACETONATES [J].
KUMAGAI, T ;
KONDO, W ;
YOKOTA, H ;
MINAMIUE, H ;
MIZUTA, S .
CHEMISTRY LETTERS, 1988, (03) :551-552
[2]  
KUMAGAI T, 1989, SERAMIKKUSU RONBUNSH, V97, P454
[3]  
MANABE T, 1990, SERAMIKKUSU RONBUNSH, V98, P77