SYNTHESIS, IR-SPECTRUM, AND CRYSTAL-STRUCTURE OF SB12O18(OH)(2)CL-22-CENTER-DOT-2CH(2)CL(2)

被引：0

作者：

WELLER, F ^{[1
]}

SCHMOCK, F ^{[1
]}

BABEL, D ^{[1
]}

DEHNICKE, K ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 04期

关键词：

ANTIMONY(V)-OXIDE CHLORIDE; SYNTHESIS; IR SPECTRA; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19956210406

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been prepared by the reaction of Sb5O7Cl11 with dichloromethane at 20 degrees C, forming colourless, moisture sensitive crystals. Sb12O18(OH)(2)Cl-22 . 2CH(2)Cl(2) crystallizes monoclinically in the space group P2(1)/n with two formula units per unit cell. Structure solution with 2696 unique observed reflections, R = 0.042. Lattice dimensions at 19 degrees C: a = 1350.2, b = 1466.7, c = 1392.9 pm, beta = 97.925 degrees. The distorted octahedrally coordinated antimony atoms, bridged by oxygen atoms, exhibit a molecular array which may be seen as a fragment of the rutile type structure, isolated by terminal chloride ligands. The solvate molecule is associated by a hydrogen bridge OH ... Cl.

引用

页码：537 / 540

页数：4

共 50 条

[21] A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)(2){PPh(o-tolyl)(2)}Cl+] [ClO4-]center dot CH2Cl2 center dot H2O
Churchill, MR
Krajkowski, LM
Huynh, MHV
Takeuchi, KJ
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (01) : 67 - 73
[22] SYNTHESIS AND CRYSTAL-STRUCTURE OF [NA(12-CROWN-4)(2)](2)[FE4SE4CL4]
AHLE, A
DEHNICKE, K
MAICHLEMOSSMER, C
STRAHLE, J
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (03): : 434 - 436
[23] CRYSTAL-STRUCTURE AND PHASE-TRANSITIONS OF [C(NH2)3]3SB2CL9.0.9H2O
ZALESKI, J
PIETRASZKO, A
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1994, 49 (09): : 895 - 901
[24] Crystal structure of cis-[Ru(bpy)(2){PPh(2)(o-tol)}Cl][ClO4]center dot 1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization
Churchill, MR
Krajkowski, LM
Huynh, MHV
Takeuchi, KJ
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (02) : 111 - 116
[25] Synthesis, Crystal Structure and Property of Cu Pb2(OH)2Cl3
黄荣荣
张素允
崔美艳
徐军
何长振
结构化学, 2015, 34 (04) : 594 - 598
[26] Synthesis, crystal structure and oxidation activity of lipoxygenase model compound [Fe(CTB)Cl] • 3CH3CH2OH • H2O
Zhao, XZ
Meng, XG
Liao, ZR
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2005, 26 (07): : 1194 - 1197
[27] THE CRYSTAL-STRUCTURE OF THE SODIUM OXOHYDROXOALUMINATE HYDRATE NA-2[AL2O3(OH)(2)]CENTER-DOT-1.5H(2)O
WEINBERGER, M
SCHNEIDER, M
MULLER, D
GESSNER, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (04): : 679 - 684
[28] SYNTHESIS AND CRYSTAL-STRUCTURE OF [NA(12-CROWN-4)2]2[HG(SE4)2] CENTER-DOT 1.5 DMF
AHLE, A
DEHNICKE, K
MACZEK, K
FENSKE, D
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (10): : 1699 - 1703
[29] Crystal structure of pentakis ethylenediammonium bis undecachlorodiantimonate(III) tetrahydrate, (NH3(CH2)(2)NH3)(5)(Sb2Cl11)(2)center dot 4H(2)O
Chaabouni, S
Kamoun, S
Daoud, A
Jouini, T
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1997, 27 (07) : 401 - 404
[30] SYNTHESIS AND CRYSTAL-STRUCTURE OF COBALT(II)-HEXAOXODIPHOSPHATE(P-P)(4-)-DODECAHYDRATE, CO2P2O6-CENTER-DOT-12H2O
HAGEN, S
JANSEN, M
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (01): : 149 - 152

← 1 2 3 4 5 →