FORMATION OF 18-MEMBERED METALLOMACROCYCLIC RINGS BY THE SULFUR-DONOR LIGAND N,N'-ETHYLENEBIS(PYRROLIDIN-2-THIONE) IN THE COMPOUNDS [CO(EBPT)BR-2](2) AND ([CU(EBPT)(2)]PF6)(N)

被引：10

作者：

ATHERTON, Z

GOODGAME, DML

KATAHIRA, DA

MENZER, S

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ligand N,N'-ethylenebis(pyrrolidin-2-thione) (ebpt) reacts with cobalt(II) bromide to form [Co(ebpt)Br-2](2) comprising discrete 18-membered rings, and with Cu(MeCN)(4)PF6 to produce polymeric {[Cu(ebpt)(2)]PF6}(n) in which there are chains of spiro-linked 18-membered rings, the ring conformation remaining unchanged.

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页码：1423 / 1424

页数：2

相关论文

共 15 条

[1]

ALRESAYES SI, 1991, J CHEM SOC CHEM COMM, P78

[2]

[Anonymous], [No title captured]

[3] INTERCONVERSION OF AU-I/II/III CENTERS IN THIOETHER MACROCYCLIC COMPLEXES - THE SYNTHESIS, STRUCTURES AND REDOX PROPERTIES OF [AU([18]ANES6)]PF6 AND [AU2([15]ANES5)(2)][B(C6F5)(4)](2) [J].

BLAKE, AJ ;

TAYLOR, A ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (13) :1097-1098

[4] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES [J].

Blake, Alexander J. ;

Schroeder, Martin .

ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 :1-80

[5] VIBRATIONAL-SPECTRA AND CRYSTAL-STRUCTURES OF TRISKIS(ETHYLENETHIOUREA)COPPER(I) AND TETRAKIS(ETHYLENETHIOUREA)COPPER(I) SYSTEMS [J].

BOWMAKER, GA ;

PAKAWATCHAI, C ;

SKELTON, BW ;

THAVORNYUTIKARN, P ;

WATTANAKANJANA, Y ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (01) :15-24

[6]

COOPER SR, 1990, STRUCT BOND, V72, P1

[7] FRAMEWORK COORDINATION CHEMISTRY - GENERALIZED ENTRY INTO A NEW CLASS OF SUPRAMOLECULAR COMPOUNDS EXEMPLIFIED BY THE STRUCTURES OF [MN2(EBPY)3(NO3)4]N[WHERE EBPY=N,N'-ETHYLENEBIS(2-PYRIDONE)] AND [ER2(EBPYRR)3(NO3)6]N[WHERE EBPYRR=N,N'-ETHYLENEBIS(2-PYRROLIDONE)] [J].

DOYLE, GA ;

GOODGAME, DML ;

HILL, SPW ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (02) :207-209

[8] CONVERSION OF ATMOSPHERIC DIOXYGEN TO A MU-ETA(2),ETA(2)-PEROXO BRIDGE IN A DINUCLEAR URANIUM(VI) COMPLEX [J].

DOYLE, GA ;

GOODGAME, DML ;

SINDEN, A ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (14) :1170-1172

[9] PREPARATION OF THE 16-ATOM RING CHELATES TRANS-[M2CL4(BUTS(CH2)5SBUT)2], M = PD OR PT - CRYSTAL-STRUCTURE OF TRANS-[PD2CL4(BUTS(CH2)5SBUT)2] [J].

ERRINGTON, J ;

MCDONALD, WS ;

SHAW, BL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (11) :2309-2311

[10] SYNTHESIS, X-RAY CHARACTERIZATION AND SPECTROSCOPIC STUDIES OF METAL-COMPLEXES OF N,N'-1,2-XYLENE-ALPHA,ALPHA'-DIYLBIS-(PYRIDIN-2-ONE) [J].

GOODGAME, DML ;

HILL, SPW ;

SMITH, AM ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (06) :859-870