THE REACTION OF FLUOROVINYL KETONES WITH CARBON NUCLEOPHILES - A NEW GENERAL-ROUTE TO ALPHA,BETA-UNSATURATED KETONES

被引：0
|
作者：
ICHIKAWA, J
YOKOTA, N
KOBAYASHI, M
MINAMI, T
机构：
来源：
SYNLETT | 1993年 / 03期
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暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2,2-Difluorovinyl ketones are quite reactive toward carbon nucleophiles such as copper and magnesium reagents, of which reaction causes the stepwise substitution of two fluorine atoms with different groups via conjugate addition-elimination process to afford fully substituted alpha,beta-unsaturated ketones in good yields.
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页码：186 / 188
页数：3
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