IN-FLOW SPECIATION OF COPPER, ZINC, LEAD AND CADMIUM IN FRESH WATERS BY DIFFERENTIAL-PULSE ANODIC-STRIPPING VOLTAMMETRY .1. OPTIMIZATION OF FILTRATION AND ENRICHMENT STEPS

被引:14
|
作者
MARTINOTTI, W
QUEIRAZZA, G
REALINI, F
CICERI, G
机构
[1] ASTA,I-20133 MILAN,ITALY
[2] CTR INFORMAZ STUDI ESPERIENZE,DIV ENVIRONM,I-20134 MILAN,ITALY
关键词
ANODIC STRIPPING VOLTAMMETRY; CADMIUM; COPPER; LEAD; PRECONCENTRATION; SPECIATION; TRACE METALS; WATERS; ZINC;
D O I
10.1016/0003-2670(92)80209-P
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An automatic system for the in situ determination of dissolved Cu, Zn, Pb and Cd in fresh waters, composed of a filtration unit, a separation and enrichment unit and an electrochemical unit for differential-pulse anodic stripping voltammetry, was investigated. The filtration and enrichment units were designed to establish the most effective experimental conditions for the measurement of metal concentrations at environmental levels. The system was built for installation in a buoy equipped with a facility for radiotransmission of obtained data.
引用
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页码:323 / 334
页数:12
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