THERMODYNAMICS OF ASSOCIATED SOLUTIONS - CORRELATION OF TERNARY EXCESS MOLAR ENTHALPIES FOR ANILINE PLUS ALKANOL PLUS BENZENE OR ACETONE MIXTURES USING THE UNIQUAC ASSOCIATED-SOLUTION MODEL

被引：9
作者：
NAGATA, I
机构：
[1] Department of Chemistry and Chemical Engineering, Division of Physical Sciences, Kanazawa University, Kanazawa, 920, 40-20
来源：
THERMOCHIMICA ACTA | 1994年 / 244卷
关键词：
ACETONE; ALKANOL; ANILINE; ASSOCIATION; BENZENE; EXCESS MOLAR ENTHALPY; MODEL; TERNARY SYSTEM; THERMODYNAMICS; UNIQUAC;
D O I：
10.1016/0040-6031(94)80203-3
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Ternary excess molar enthalpies are reported for 1-propanol + aniline + acetone at 25 degrees C. The UNIQUAC associated-solution model with ternary parameters is used to correlate ternary excess molar enthalpies for aniline + alkanol + benzene or acetone mixtures. The model gives appreciably smaller deviations between the calculated and experimental results than those obtained using polynomial equations.
引用
收藏
页码：21 / 32
页数：12
相关论文
共 25 条
[1]  
Acree W., 1984, THERMODYNAMIC PROPER
[2]  
Christensen C., 1984, DECHEMA CHEM DATA SE
[3]   THERMODYNAMICS OF ALCOHOL-SOLUTIONS - PHASE-EQUILIBRIA OF BINARY AND TERNARY MIXTURES CONTAINING 2 ALCOHOLS [J].
NAGATA, I ;
OHTSUBO, K .
THERMOCHIMICA ACTA, 1986, 102 :185-205
[4]   THERMODYNAMICS OF ALCOHOL-SOLUTIONS - EXCESS MOLAR ENTHALPIES OF TERNARY MIXTURES CONTAINING 2 ALCOHOLS AND ONE ACTIVE NONASSOCIATING COMPONENT [J].
NAGATA, I ;
TAMURA, K ;
GOTOH, K .
THERMOCHIMICA ACTA, 1986, 104 :179-202
[5]   THERMODYNAMICS OF ALCOHOL-UNASSOCIATED ACTIVE COMPONENT LIQUID-MIXTURES [J].
NAGATA, I ;
KAWAMURA, Y .
CHEMICAL ENGINEERING SCIENCE, 1979, 34 (05) :601-611
[6]   EXCESS-ENTHALPIES OF (ANILINE PLUS PROPAN-2-OL) AND OF (ANILINE PLUS PROPAN-2-OL PLUS BENZENE) AT THE TEMPERATURE 298.15-K [J].
NAGATA, I ;
MIYAZAKI, K .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (11) :1175-1180
[7]   PREDICTION OF EXCESS HEAT-CAPACITIES OF ALCOHOL-HYDROCARBON MIXTURES [J].
NAGATA, I ;
YAMADA, T .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1973, 18 (01) :87-90
[8]   EXCESS MOLAR ENTHALPIES FOR 1-PROPANOL PLUS ACETONE AND 1-PROPANOL PLUS ACETONE PLUS BENZENE MIXTURES AT 298.15 K [J].
NAGATA, I ;
TAKEUCHI, K .
THERMOCHIMICA ACTA, 1994, 242 :103-110
[9]   CORRELATION AND PREDICTION OF EXCESS THERMODYNAMIC FUNCTIONS OF STRONGLY NONIDEAL LIQUID-MIXTURES [J].
NAGATA, I ;
YAMADA, T .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1974, 13 (01) :47-53
[10]   TERNARY EXCESS MOLAR ENTHALPIES OF CHLOROFORM PLUS ACETONE PLUS CYCLOHEXANE MIXTURES AT 298.15-K [J].
NAGATA, I ;
TAMURA, K ;
OZAKI, S ;
MYOHEN, K .
THERMOCHIMICA ACTA, 1992, 209 :31-41
123