Coordinatively saturated Pt(II) complexes as potential precursors of organometallic polymers

被引：12
|
作者：
Giordano, F
Panunzi, B
Roviello, A
Ruffo, F
机构：
[1] Dipartimento di Chimica, Università di Napoli 'Federico II', I-80134 Naples
来源：
INORGANICA CHIMICA ACTA | 1995年 / 239卷 / 1-2期
关键词：
platinum complexes; pentacoordinated complexes; C-C activation; crystal structures;
D O I：
10.1016/0020-1693(95)04723-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of stable Pt(II) coordinatively saturated derivatives suitable as precursors of organometallic polymers is described. Compounds of the type [PtX(2)(dmphen) (olefin)] (X = CN, SCN; dmphen = 2,9-Me(2)-1,10-phenanthroline) are obtained by oxidative addition to Pt(0) species. The unprecedent fission of activated carbon-carbon bonds to give 18 e(-) Pt(II) species is described. The solid state structure of [Pt(SCN)(2)(dmphen) (dimethylmaleate)] has been determined by X-ray crystallography. Vinyl monomers [PtCl(RCH=CH2)-(dmphen)(dimethylmaleate)] (R = CO2, CH2CO2) have also been obtained.
引用
收藏
页码：61 / 66
页数：6
相关论文
共 50 条
  • [41] Potential of organometallic complexes in medicinal chemistry
    Qader, Sarbaz Mohammed
    Mohammed, Azhin Hamad
    Muhammed, Akar Mahmood
    Omer, Rebaz Anwar
    Abdulkareem, Eman Ibraheem
    Rashid, Rzgar Faruq
    REVIEWS IN INORGANIC CHEMISTRY, 2024,
  • [42] INTERACTION BETWEEN MERCURIC CYANIDE AND COORDINATIVELY SATURATED INERT CYANO COMPLEXES .1.
    BECK, M
    PORZSOLT, E
    MAGYAR KEMIAI FOLYOIRAT, 1971, 77 (10): : 543 - &
  • [43] The potential of organometallic complexes in medicinal chemistry
    Gasser, Gilles
    Metzler-Nolte, Nils
    CURRENT OPINION IN CHEMICAL BIOLOGY, 2012, 16 (1-2) : 84 - 91
  • [44] Targeted Synthesis and Study of the Structure of Coordinatively Saturated Calcium, Strontium, and Barium β-Diketonate Complexes
    V. K. Khamylov
    T. S. Pochekutova
    B. I. Petrov
    S. P. Lukina
    G. K. Fukin
    S. Ya. Khorshev
    Yu. A. Kurskii
    Doklady Chemistry, 2005, 403 : 132 - 135
  • [45] Targeted synthesis and study of the structure of coordinatively saturated calcium, strontium, and barium β-diketonate complexes
    Khamylov, VK
    Pochekutova, TS
    Petrov, BI
    Lukina, SP
    Fukin, GK
    Khorshev, SY
    Kurskii, YA
    DOKLADY CHEMISTRY, 2005, 403 (1-3) : 132 - 135
  • [46] Supramolecular trapping of phosphanes by cyclodextrins: A general approach to generate phosphane coordinatively unsaturated organometallic complexes
    Binkowski-Machut, C
    Canipelle, M
    Bricout, H
    Tilloy, S
    Hapiot, F
    Monflier, E
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 8 (08) : 1611 - 1619
  • [47] ORGANOMETALLIC COMPLEXES OF MOLYBDENUM AND TUNGSTEN AS CATALYST PRECURSORS IN DISPROPORTIONATION OF PROPENE
    SMITH, J
    MOWAT, W
    WHAN, DA
    EBSWOTH, EAV
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (16): : 1742 - 1746
  • [48] Synthesis of ferromagnetic Mn-Pt nanoparticles from organometallic precursors
    Ono, K
    Okuda, R
    Ishii, Y
    Kamimura, S
    Oshima, M
    JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (09): : 1941 - 1942
  • [49] Transition metal isocyanide complexes as precursors for organometallic supramolecules.
    Guo, JH
    Mayr, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 273 - INOR
  • [50] Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes
    Mason, Kevin
    Harnden, Alice C.
    Patrick, Connor W.
    Poh, Adeline W. J.
    Batsanov, Andrei S.
    Suturina, Elizaveta A.
    Vonci, Michele
    McInnes, Eric J. L.
    Chilton, Nicholas F.
    Parker, David
    CHEMICAL COMMUNICATIONS, 2018, 54 (61) : 8486 - 8489
12345